Preview

Doklady BGUIR

Advanced search

Optical Properties of Composites of Polymethylmethacrylate and Polyethylene with Micron Particles of Graphitic Carbon Nitride

https://doi.org/10.35596/1729-7648-2026-24-3-36-43

Abstract

Film heterostructures made of polymethyl methacrylate and low-density polyethylene with incorporated micron-sized particles of a semiconductor (graphite-like carbon nitride g-C3N4), fabricated using a component mixing and casting technique, were studied. Such heterostructures are relevant for the creation of new environmentally friendly optical elements for information processing. Free-standing continuous films based on polymethyl methacrylate and low-density polyethylene with a thickness of 30–50 μm and porous films based on polymethyl methacrylate with a thickness of 50–500 μm were created. The content of the added semiconductor was 5 wt.%, which ensured their integrity and mechanical stability during transportation and subsequent studies. Based on the optical transmission spectra of these films and their photoluminescence, it was established that g-C3N4 incorporated into the studied polymer matrices retains its size and semiconductor properties. The particles are distributed quasi-uniformly in the synthesized materials. It was found that the transmission spectra of the studied heterostructures have a quasi-linear dependence of the intensity of transmitted radiation on the wavelength of the incident radiation, which can be used in photonics to create spectrally sensitive elements.

About the Authors

S. Maksimov
Belarusian State University of Informatics and Radioelectronics
Belarus

Maksimov Sergei, Electronics Engineer at the Center 4.11

220013, Minsk, P. Brovki St., 6

Тel.: +375 29 612-92-19



V. Shaposhnikov
Belarusian State University of Informatics and Radioelectronics
Belarus

Shaposhnikov V., Cand. Sci. (Phys. and Math.), Leading Researcher at the Center 4.11

Minsk



V. Borisenko
Belarusian State University of Informatics and Radioelectronics
Belarus

Borisenko V., Dr. Sci. (Phys. and Math.), Professor, Professor of the Department of Micro- and Nanoelectronics

Minsk



References

1. Baglov A. V., Chubenko E. B., Hnitsko A. A., Borisenko V. E., Malashevich A. A., Uglov V. V. (2020) Structural and Photoluminescent Properties of Graphite-Like Carbon Nitride. Semiconductors. 54 (2), 176–180. DOI: 10.21883/0000000000 (in Russian).

2. Chubenko E. B., Baglov A. V., Fedotova Yu. A., Borisenko V. E. (2021) Synthesis of Graphitic Carbon Nitride on the Surface of Nanoparticles Fe3O4. Inorganic Materials. 57 (2), 144–149. DOI: 10.31857/S0002337X21020056 (in Russian).

3. Chen Z., Zhang S., Liu Y., Alharbi N. S., Rabah S. O., Wang S., et al. (2020) Synthesis and Fabrication of g-C3N4-Based Materials and Their Application in Elimination of Pollutants. Science of the Total Environment. 731. https://doi.org/10.1016/j.scitotenv.2020.139054.

4. Vasile C. (2018) Polymeric Nanocomposites and Nanocoatings for Food Packaging. Materials. 11 (10). https://doi.org/10.3390/ma11101834.

5. Unalan I. U., Cerri G., Marcuzzo E., Cozzolino C. A., Farris S. (2014) Nanocomposite films and Coatings Using Inorganic Nanobuilding Blocks (NBB): current applications and future opportunities in the Food Packaging Sector. RSC Advances. 4 (56), 29393–29428. DOI: 10.1039/C4RA01778A.

6. Vlasova T. V., Kryshtob V. I., Mironov V. F., Apresyan L. A., Bokova S. N., Obraztsova E. D., et al. (2011) Solution Casting Method for PVC Nanocomposites with Functionalized Single-Walled Carbon Nanotubes. arXiv preprint arXiv:1112.2062.

7. Chubenko E. B., Baglov A. V., Leonenya M. S., Yablonskii G. P., Borisenko V. E. (2020) Structure of the Photoluminescence Spectra of Oxygen-Doped Graphitic Carbon Nitride. Zhurnal Prikladnoii Spektroskopii. 87 (1), 14–20 (in Russian).

8. Das D., Shinde S. L., Nanda K. K. (2016) Temperature-Dependent Photoluminescence of g-C3N4: Implication for Temperature Sensing. ACS Applied Materials & Interfaces. 8 (3), 2181–2186. DOI: 10.1021/acsami.5b10770.

9. Gan Z., Shan Y., Chen J., Gui Q., Zhang Q., Nie S., et al. (2016) The Origins of the Broadband Photoluminescence from Carbon Nitrides and Applications to White Light Emitting. Nano Research. 9 (6), 1801–1812. DOI: 10.1007/s12274-016-1073-2.

10. Nguyen Van M., Mai O. L. T., Pham Do C., Lam Thi H., Pham Manh C., Nguyen Manh H., et al. (2020) Fe-Doped g-C3N4: High-Performance Photocatalysts in Rhodamine B Decomposition. Polymers. 12 (9). https://doi.org/10.3390/polym12091963.


Review

For citations:


Maksimov S., Shaposhnikov V., Borisenko V. Optical Properties of Composites of Polymethylmethacrylate and Polyethylene with Micron Particles of Graphitic Carbon Nitride. Doklady BGUIR. 2026;24(3):36-43. (In Russ.) https://doi.org/10.35596/1729-7648-2026-24-3-36-43

Views: 28

JATS XML


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 1729-7648 (Print)
ISSN 2708-0382 (Online)