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Сomposition, structure and functional properties of silver-tungsten composition electrochemistry coatings formed with the help of ultrasound

https://doi.org/10.35596/1729-7648-2021-19-6-23-31

Abstract

Influence of electrolyte composition and deposition parameters on the composition, structure, physicalmechanical and functional properties of composite silver-tungsten coatings was studied. It was shown that addition of sodium tungstate in electrolyte and application of ultrasound at the electroplating leads to formation of silver layers that contains tungsten oxides and demonstrates lower crystalline nucleus. Application of ultrasound vibration at the electrochemical deposition increases ability for plating process control and allows to optimize electrophysical and functional properties of composite electrochemical coatings, to make dense fine crystalline thin layers. Obtained layers demonstrate increased microhardness (by 10–50 %), wear resistance (1,5–2 times), corrosion resistance and improved contact electrical resistance. It is shown that application of ultrasound effect to electrodeposition allows increased level of permissible current density and provides.

About the Authors

N. V. Bogush
Belarusian State University of Informatics and Radioelectronics
Belarus

Bogush Natalia V., Researcher of R&D Department

220013, Minsk, P. Brovka str., 6



A. A. Khmyl
Belarusian State University of Informatics and Radioelectronics
Belarus

Khmyl Alexandr A., D.Sc., Professor

Minsk



L. K. Kushner
Belarusian State University of Informatics and Radioelectronics
Belarus

Kushner Larissa K., Senior Researcher of R&D Department

Minsk



N. V. Dezhkunov
Belarusian State University of Informatics and Radioelectronics
Belarus

Dezhkunov Nikolay V., PhD, Assistant Professor, Head of the Laboratory 5.4

Minsk



References

1. Kushner L.K., Kuzmar I.I., Khmyl A.A., Dezkunov N.V. Nanocomposite nickel plating under non-stationary electrolysis. Nanoscience and Technology: An International Journal. Special Issue: Fullerenes and Nanostructures in Condensed Matter. 2019;10(4):355-363.

2. Bogush N.V., Khmyl A.A., Kushner L.K. [Structure and physical-mechanical properties electroplated of AG-W composition coatings]. Doklady BGUIR = Doklady BGUIR. 2017;5(107):54-61. (In Russ.)

3. Dezkunov N.V. [Equipment for ultrasonic intensification of galvanic technological processes]. Materials of reports III RSTS “Creation of new and improvement of existing technologies and equipment, application of electroplating and their replacement coatings”, 5–6 Dec. 2013, Minsk, Belarus. Minsk: BSTU; 2013:82-86. (In Russ.)

4. Vasilec V.K. [Influence of parameters of electric current and ultrasonic vibrations on the microstructure and properties of electrochemical coatings with a tin-bismuth alloy]. Problems of physics, mathematics and technology. 2016;3(28):7-12. (In Russ.)

5. Khmyl A.A. [Influence of ultrasound on the corrosion resistance of electroplated coatings]. Modern means of communication: materials of XVII International scientific and technical conference, 16–18 oct. 2012, Minsk, Belarus. Minsk: VGКS; 2012:150-151. (In Russ.)


Review

For citations:


Bogush N.V., Khmyl A.A., Kushner L.K., Dezhkunov N.V. Сomposition, structure and functional properties of silver-tungsten composition electrochemistry coatings formed with the help of ultrasound. Doklady BGUIR. 2021;19(6):23-31. (In Russ.) https://doi.org/10.35596/1729-7648-2021-19-6-23-31

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ISSN 1729-7648 (Print)
ISSN 2708-0382 (Online)