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Electrophysical properties of vanadium oxide films deposited by reactive magnetron sputtering

https://doi.org/10.35596/1729-7648-2020-18-6-94-102

Abstract

The aim of this work was to study the effect of the gas composition during sputtering on the electrophysical properties of vanadium oxide films deposited by pulsed reactive magnetron sputtering of a vanadium target in an Ar/O2 medium of working gases.

The dependences of the magnetron discharge voltage, deposition rate, resistivity, temperature coefficient of resistance (TCR), and the band gap of vanadium oxide films on the oxygen concentration in the gas mixture are obtained. It was found that amorphous films of vanadium oxide are formed during reactive magnetron sputtering. It is shown that the properties of the deposited vanadium oxide films have a strong dependence on the oxygen concentration in the Ar/O2 gas mixture, which is associated with the formation of a mixture of various intermediate vanadium oxides in the film. It was found that from the point of view of using vanadium oxide films as thermosensitive layers of microbolometers, the films must be deposited at oxygen concentrations in the gas mixture of 17 to 25 %. At the given oxygen concentrations without heating the substrates, vanadium oxide films with a resistivity (0.6–4.0)·10-2 Ohm·m, TCR 2.2–2.3%/°C and a band gap for direct transitions of 3.7–3.78 eV. The obtained characteristics make it possible to use these films as thermosensitive layers of microbolometers.

About the Authors

T. D. Nguen
Belarusian State University of Informatics and Radioelectronics
Belarus

PG student of Electronic Technique and Technology Department

Minsk



A. I. Zanko
JSC “Integral” – “Integral” Holding Managing Company
Belarus

Process Engineer

Minsk



D. A. Golosov
Belarusian State University of Informatics and Radioelectronics
Belarus

Golosov Dmitriy Anatol’evich, PhD, Associate Professor, Leader Researcher of Center 9.1 of R&D Department

220013, Republic of Belarus, Minsk, P. Brovki str., 6

tel. +375-29-671-35-43



S. M. Zavadski
Belarusian State University of Informatics and Radioelectronics
Belarus

PhD, Associate Professor, Head of Center 9.1 of R&D Department

Minsk



S. N. Melnikov
Belarusian State University of Informatics and Radioelectronics
Belarus

PhD, Leader Researcher of Center 9.1 of R&D Department

Minsk



V. V. Kolos
JSC “Integral” – “Integral” Holding Managing Company
Belarus

Deputy Head of the Industry Laboratory of New Technologies and Materials

Minsk



References

1. Rogalski A. Infrared Detectors for the Future. Acta physica polonica A. 2009;116(3):389-406.

2. Breen Th.B., Kohin M., Marshall Ch. A., Murphy R., White T.E., Leary A.R., Parker T.W. Even more applications of uncooled microbolometer sensors. Proc. SPIE. 1999;3698:308-319.

3. Mauger А, Julien Ch. M. Review V2O5 thin films for energy storage and conversion. AIMS Materials Science. 2018;5(3):349-401. DOI: 10.3934/matersci.2018.3.349.

4. Singh T., Wang Sh., Aslam N., Zhang H., Hoffmann-Eifert S., Mathur S. Atomic Layer Deposition of Transparent VOx Thin Films for Resistive Switching Applications. Chemical Vapor Deposition. 2014;20(7-9):291-297. DOI: 10.1002/cvde.201407122.

5. Esther A.C.M., Sharma A.K., Dey A., Porwal D., Pradeepkumar M.S., Rangappa D. Optical constants of pulsed RF magnetron nanocolumner V2O5 coating. Physica B. 2015;478:161-166.

6. Luo Z., Wu Z., Xu X., Du M., Wang T., Jiang Y. Impact of substrate temperature on the microstructure, electrical and optical properties of sputtered nanoparticles V2O5 thin film. Vacuum. 2010;85(2):145-150.

7. Patil C.E., Tarwal N.L., Shinde P.S., Deshmukh H.P., Patil P.S. Synthesis of electrochromic vanadium oxide by pulsed spray pyrolysis technique and its properties. Journal of Physics D. Applied Physics. 2009;42(2):1-6.

8. Kumar A., Singh P., Kulkarni N., Kaur D. Structural and optical studies of nanocrystalline V2O5 thin film. Thin Solid Film. 2008;516(6):912-918.

9. Beke S. А review of the growth of V2O5 films from 1885 to 2010. Thin Solid Films. 2011;519(6):1761-1771.

10. Chen S., Jianjun L., Jun D., Hong M., Hongchen W., Xinjian Y. Characterization of nanostructured VO2 thin films grown by magnetron controlled sputtering deposition and post annealing method. Optics Express. 2009;17(26):24153-24161.

11. Zhang H., Wu Z., Yan D., Xu X., Jiang Y. Tunable hysteresis in metal-insulator transition of nanostructured vanadium oxide thin films deposited by reactive direct current magnetron sputtering. Thin Solid Films. 2014;552:218-224.


Review

For citations:


Nguen T.D., Zanko A.I., Golosov D.A., Zavadski S.M., Melnikov S.N., Kolos V.V. Electrophysical properties of vanadium oxide films deposited by reactive magnetron sputtering. Doklady BGUIR. 2020;18(6):94-102. (In Russ.) https://doi.org/10.35596/1729-7648-2020-18-6-94-102

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ISSN 1729-7648 (Print)
ISSN 2708-0382 (Online)