bsuirДоклады БГУИРDoklady BGUIR1729-76482708-0382БГУИР10.35596/1729-7648-2025-23-5-27-34bsuir-4204Research ArticleСтатьиПолупроводниковые твердые растворы Cu2FeSn(Sx,Se1–x)4: синтез, структурные свойства, диаграмма состоянияSemiconductor Solid Solutions Cu2FeSn(Sx,Se1–x)4: Synthesis, Structural Properties, State DiagramХорошкоВ. В.KhoroshkoV. V.

Хорошко Виталий Викторович, канд. техн. наук, доц., зав. каф. проектирования информационно-компьютерных систем,

220013, Минск, ул. П. Бровки, 6.

Тел.: +375 44 737-99-99.

Vitaliy V. Khoroshko, Сand. Sci. (Tech.), Associate Professor, Chair of Department of Information and Computer Systems Design, 

6, P. Brovki St., Minsk, 220013.

Тel.: +375 44 737-99-99.

khoroshko@bsuir.byОсмоловскаяТ. Н.OsmolovskayaT. N.

Осмоловская Т. Н., аспирант, 

Минск.

Tatiana N. Osmolovskaya, Postgraduate of the SPC NAS of Belarus,

Minsk.

СтанчикА. В.StanchikA. V.

Станчик А. В., канд. физ.-мат. наук, доц., вед. науч. сотр., 

Минск.

Aliona V. Stanchik, Сand. Sci. (Phys. and Math.), Associate Professor, Leading Researcher, 

Minsk.

ПугачН. Г.PugachN. G.

Пугач Н. Г., канд. физ.-мат. наук, проф. департамента электронной инженерии, 

Москва.

Natalia G. Pugach, Сand. Sci. (Phys. and Math.), Professor of the Department of Electronic Engineering, 

Moscow.

ДорошкевичА. С.DoroshkevichA. S.

Дорошкевич А. С., канд. физ.-мат. наук, доц., нач. группы сектора исследований, 

Дубна.

Alexandr S. Doroshkevich, Сand. Sci. (Phys. and Math.), Associate Professor, Head of the Research Sector Group, 

Dubna.

РадюшЮ. В.RadyushYu. V.

Радюш Ю. В., канд. физ.-мат. наук, доц., вед. науч. сотр.,

Минск. 

Yuri V. Radyush, Сand. Sci. (Phys. and Math.), Associate Professor, Leading Researcher,

Minsk.

КузьмарИ. И.KuzmarI. I.

Кузьмар И. И., канд. техн. наук, доц., зав. лаб. «Импульсный электролиз и многокомпонентные материалы»,

Минск.

Inna I. Kuzmar, Сand. Sci. (Tech.), Associate Professor, Head of the Laboratory “Pulse Electrolysis and Multicomponent Materials”, 

Minsk.

ЛоскоЕ. В.LoskaA. U.

Лоско Е. В., инженер; аспирант

Минск.

Alena U. Loska, Engineer; Postgraduate Student,

Minsk.

Белорусский государственный университет информатики и радиоэлектроники (БГУИР)Belarusian State University of Informatics and Radioelectronics (BSUIR)Белорусский государственный университет информатики и радиоэлектроники (БГУИР); Научно-практический центр Национальной академии наук Беларуси по материаловедению (НПЦ НАН Беларуси)Belarusian State University of Informatics and Radioelectronics (BSUIR); Scientific and Practical Center of the National Academy of Sciences of Belarus for Materials Science (SPC NAS of Belarus)Научно-практический центр Национальной академии наук Беларуси по материаловедению (НПЦ НАН Беларуси)Scientific and Practical Center of the National Academy of Sciences of Belarus for Materials Science (SPC NAS of Belarus)Национальный исследовательский университет «Высшая школа экономики»National Research University Higher School of EconomicsОбъединенный институт ядерных исследованийJoint Institute for Nuclear ResearchОАО «НИИЭВМ»; Белорусский государственный университет информатики и радиоэлектроники (БГУИР)ОJSС “NIIEVM”; Belarusian State University of Informatics and Radioelectronics (BSUIR)2025291020252352734Copyright © Хорошко В.В., Осмоловская Т.Н., Станчик А.В., Пугач Н.Г., Дорошкевич А.С., Радюш Ю.В., Кузьмар И.И., Лоско Е.В., 20252025Хорошко В.В., Осмоловская Т.Н., Станчик А.В., Пугач Н.Г., Дорошкевич А.С., Радюш Ю.В., Кузьмар И.И., Лоско Е.В.Khoroshko V.V., Osmolovskaya T.N., Stanchik A.V., Pugach N.G., Doroshkevich A.S., Radyush Y.V., Kuzmar I.I., Loska A.U.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://doklady.bsuir.by/jour/article/view/4204

В статье представлены результаты получения крупноблочных поликристаллов системы полупроводниковых твердых растворов Cu2FeSn(Sx,Se1–x)4, образующихся во всем диапазоне концентраций. Установлено, что как соединения Cu2FeSnS4, Cu2FeSnSe4, так и твердые растворы имеют тетрагональную структуру станнита I42̅ m с соотношением параметров элементарной ячейки с/а ∼ 2. Параметры элементарной ячейки изменялись линейно в соответствии с законом Вегарда – от a = (5,704 ± 0,005) Å и с = (11,26 ± 0,01) Å для Cu2FeSnSe4 до a = (5,441 ± 0,005) Å и с = (10,72 ± 0,01) Å для Cu2FeSnS4. Установлены зависимости рентгеновской плотности и температуры Дебая. По результатам дифференциального термического анализа определены температуры плавления образцов, построена диаграмма состояния системы.

The article presents the results of obtaining large-block polycrystals of the semiconductor solid solution system Cu2FeSn(Sx,Se1–x)4, formed in the entire concentration range. It was found that both the compounds Cu2FeSnS4, Cu2FeSnSe4 and the solid solutions have a tetragonal stannite structure I4̅2m with a ratio of the unit cell parameters с/а ∼ 2. The unit cell parameters varied linearly in accordance with Vegard’s law – from a = (5.704 ± 0.005) Å and c = (11.261 ± 0.01) Å for Cu2FeSnSe4 to a = (5.441 ± 0.005) Å and c = (10.72 ± 0.01) Å for Cu2FeSnS4. The dependences of the X-ray density and the Debye temperature were determined. Based on the results of differential thermal analysis, the melting temperatures of the samples were determined and a system phase diagram was constructed.

станнитразбавленные магнитные полупроводникикристаллическая структурадиаграмма состоянияstannitedilute magnetic semiconductorscrystal structurestate diagramИсследование выполнено в рамках Государственной программы научных исследований «Материаловедение, новые материалы и технологии», подпрограммы «Физика конденсированного состояния и создание новых функциональных материалов и технологий их получения».ReferencesJing B., Ji J., Hao L., Yang T., Tan E. (2020) DFT Investigation on the Electronic, Magnetic, Mechanical Properties and Strain Effects of the Quaternary Compound Cu2FeSnS4. Crystals. 10 (6), 1–12. https://doi:10.3390/cryst10060509.Jing B., Ji J., Hao L., Yang T., Tan E. (2020) DFT Investigation on the Electronic, Magnetic, Mechanical Properties and Strain Effects of the Quaternary Compound Cu2FeSnS4. Crystals. 10 (6), 1–12. https://doi:10.3390/cryst10060509.Rincón C., Quintero M., Moreno E., Power Ch., Quintero E., Henao J. A., et al. (2011) X-Ray Diffraction, Raman Spectrum and Magnetic Susceptibility of the Magnetic Semiconductor Cu2FeSnS4. Solid State Communications. 151 (13), 947–951. https://doi.org/10.1016/j.ssc.2011.04.002.Rincón C., Quintero M., Moreno E., Power Ch., Quintero E., Henao J. A., et al. (2011) X-Ray Diffraction, Raman Spectrum and Magnetic Susceptibility of the Magnetic Semiconductor Cu2FeSnS4. Solid State Communications. 151 (13), 947–951. https://doi.org/10.1016/j.ssc.2011.04.002.Xiaolu L., Xianhua W., Daocheng P. (2012) Dilute Magnetic Semiconductor Cu2FeSnS4 Nanocrystals with a Novel Zincblende Structure. Journal of Nanomaterials. 12. https://doi.org/10.1155/2012/708648.Xiaolu L., Xianhua W., Daocheng P. (2012) Dilute Magnetic Semiconductor Cu2FeSnS4 Nanocrystals with a Novel Zincblende Structure. Journal of Nanomaterials. 12. https://doi.org/10.1155/2012/708648.Ghemud, V. S., Jadhav P. R., Kolhe P. T., Shelke P. N., Dahiwale S. S., Kshirsagar A. (2023) Experimental and Computational Study of Cu2FeSnS4: An Emerging Quaternary Semiconductor. Optical Materials. 142. https://doi.org/10.1016/j.optmat.2023.114123.Ghemud, V. S., Jadhav P. R., Kolhe P. T., Shelke P. N., Dahiwale S. S., Kshirsagar A. (2023) Experimental and Computational Study of Cu2FeSnS4: An Emerging Quaternary Semiconductor. Optical Materials. 142. https://doi.org/10.1016/j.optmat.2023.114123.El Khouja O., Negrila C. C., Nouneh K., Secu M., Ebn Touhami M., Matei E., et al. (2022) Bulk and Surface Characteristics of Co-Electrodeposited Cu2FeSnS4 Thin Films Sulfurized at Different Annealing Temperatures. Journal of Alloys and Compounds. 906. https://doi.org/10.1016/j.jallcom.2022.164379.El Khouja O., Negrila C. C., Nouneh K., Secu M., Ebn Touhami M., Matei E., et al. (2022) Bulk and Surface Characteristics of Co-Electrodeposited Cu2FeSnS4 Thin Films Sulfurized at Different Annealing Temperatures. Journal of Alloys and Compounds. 906. https://doi.org/10.1016/j.jallcom.2022.164379.Salla J. S., Silvestri S., de Moraes Flores E. M., Foletto E. L. (2018) A Novel Application of Cu2FeSnS4 Particles Prepared by Solvothermal Route as Solar Photo-Fenton Catalyst. Materials Letters. 228, 160–163. https://doi.org/10.1016/j.matlet.2018.06.004.Salla J. S., Silvestri S., de Moraes Flores E. M., Foletto E. L. (2018) A Novel Application of Cu2FeSnS4 Particles Prepared by Solvothermal Route as Solar Photo-Fenton Catalyst. Materials Letters. 228, 160–163. https://doi.org/10.1016/j.matlet.2018.06.004.Dhiman V., Kumar S., Kaur M., Sharma R., Chandel T., Bhardwaj D., et al. (2023) Synergistic Effect of Stirring and Marigold Shaped Cu2FeSnS4 Nanostructure for the Enhanced Performance of Rhodamine B Degradation Under Visible Light. Inorganic Chemistry Communications. 154. https://doi.org/10.1016/j.inoche.2023.110923.Dhiman V., Kumar S., Kaur M., Sharma R., Chandel T., Bhardwaj D., et al. (2023) Synergistic Effect of Stirring and Marigold Shaped Cu2FeSnS4 Nanostructure for the Enhanced Performance of Rhodamine B Degradation Under Visible Light. Inorganic Chemistry Communications. 154. https://doi.org/10.1016/j.inoche.2023.110923.Sahoo M. K., Gusain M., Thangriyal S., Nagarajan R., Ranga Rao G. (2020) Energy Storage Study of Trimetallic Cu2MSnS4 (M: Fe, Co, Ni) Nanomaterials Prepared by Sequential Crystallization Method. Journal of Solid State Chemistry. 282. https://doi.org/10.1016/j.jssc.2019.121049.Sahoo M. K., Gusain M., Thangriyal S., Nagarajan R., Ranga Rao G. (2020) Energy Storage Study of Trimetallic Cu2MSnS4 (M: Fe, Co, Ni) Nanomaterials Prepared by Sequential Crystallization Method. Journal of Solid State Chemistry. 282. https://doi.org/10.1016/j.jssc.2019.121049.Inamdar A. I., Salunke A. S., Hou B., Shrestha N. K., Im H., Kim H. (2023) Highly Durable and Sustainable Copper-Iron-Tin-Sulphide (Cu2FeSnS4) Anode for Li-Ion Batteries: Effect of Operating Temperatures. Dalton Transactions. 34 (52), 12020–12029. https://doi.org/10.1039/D3DT01338C.Inamdar A. I., Salunke A. S., Hou B., Shrestha N. K., Im H., Kim H. (2023) Highly Durable and Sustainable Copper-Iron-Tin-Sulphide (Cu2FeSnS4) Anode for Li-Ion Batteries: Effect of Operating Temperatures. Dalton Transactions. 34 (52), 12020–12029. https://doi.org/10.1039/D3DT01338C.Quintero M., Moreno E., Alvarez S., Marquina J., Rincón C., Quintero E., et al. (2014) Lattice Parameter Values and Phase Transitions for the Cu2-II-IV-S4(Se4) (II=Mn, Fe, Co; IV=Si, Ge, Sn) Magnetic Semiconductor Compounds. Revista Latinoamericana de Metalurgia y Materiales. 34 (1), 28–38.Quintero M., Moreno E., Alvarez S., Marquina J., Rincón C., Quintero E., et al. (2014) Lattice Parameter Values and Phase Transitions for the Cu2-II-IV-S4(Se4) (II=Mn, Fe, Co; IV=Si, Ge, Sn) Magnetic Semiconductor Compounds. Revista Latinoamericana de Metalurgia y Materiales. 34 (1), 28–38.Zhou B., Yan X., Li P., Yang L., Yu D. (2015) Raman Spectroscopy as a Superior Tool to Understand the Synthetic Pathway of Cu2FeSnS4 Nanoparticles. European Journal of Inorganic Chemistry. 16, 2690–2694. https://doi.org/10.1002/ejic.201500189.Zhou B., Yan X., Li P., Yang L., Yu D. (2015) Raman Spectroscopy as a Superior Tool to Understand the Synthetic Pathway of Cu2FeSnS4 Nanoparticles. European Journal of Inorganic Chemistry. 16, 2690–2694. https://doi.org/10.1002/ejic.201500189.Ahmadi S., Khemiri N., Cantarero A., Kanzari M. (2024) Effect of Calcination on the Structural, Morphological and Optical Properties of Earth Abundant Cu2FeSnS4 Powders Prepared by Solid-State Reaction. Journal of Solid State Chemistry. 339. https://doi.org/10.1016/j.jssc.2024.124969.Ahmadi S., Khemiri N., Cantarero A., Kanzari M. (2024) Effect of Calcination on the Structural, Morphological and Optical Properties of Earth Abundant Cu2FeSnS4 Powders Prepared by Solid-State Reaction. Journal of Solid State Chemistry. 339. https://doi.org/10.1016/j.jssc.2024.124969.Quintero M., Barreto A., Grima P., Tovar R., Quintero E., Sánchez Porras G., et al. (1999) Crystallographic Properties of I2-Fe-IV-VI4 Magnetic Semiconductor Compounds. Materials Research Bulletin. 34 (14–15), 2263–2270. https://doi.org/10.1016/S0025-5408(00)00166-5.Quintero M., Barreto A., Grima P., Tovar R., Quintero E., Sánchez Porras G., et al. (1999) Crystallographic Properties of I2-Fe-IV-VI4 Magnetic Semiconductor Compounds. Materials Research Bulletin. 34 (14–15), 2263–2270. https://doi.org/10.1016/S0025-5408(00)00166-5.Lindemann F. (1910) About the Сalculation of Molecular Own Frequencies. Physical Magazine. 11 (14), 609–612.Lindemann F. (1910) About the Сalculation of Molecular Own Frequencies. Physical Magazine. 11 (14), 609–612.Sánchez Porras G., Quintero M., Wasim. S. M. (1990) Journal of Applied Physics Electrical Properties of (CuIn)1−zMn2zTe2 Alloys. Applied Physics. 67 (7), 3382–3386. https://doi.org/10.1063/1.345349Sánchez Porras G., Quintero M., Wasim. S. M. (1990) Journal of Applied Physics Electrical Properties of (CuIn)1−zMn2zTe2 Alloys. Applied Physics. 67 (7), 3382–3386. https://doi.org/10.1063/1.345349

The authors declare that there are no conflicts of interest present.